Tracing Catalytic Conversion on Single Zeolite Crystals in 3D with Nonlinear Spectromicroscopy
نویسندگان
چکیده
منابع مشابه
Synthesis and Catalytic Performance of Large Zeolite Y Crystals
1. Introduction Zeolites have gained an irreplaceable role as catalysts in the refining industry. With a production capacity of 625·10 6 t in 2004, the fluid catalytic cracking process (FCC) represents the second most important heterogeneously catalyzed process [1]. As an active component, the catalyst of this process contains zeolite H-Y. Since a high-molecular feed is used, a detailed knowled...
متن کاملMode conversion in quadratic nonlinear crystals.
We propose a novel all-optical, nonlinear mode-conversion scheme based on cascaded three-wave-mixing phase-matched interactions in quadratic nonlinear crystals. We demonstrate the method experimentally by performing all-optical mode conversion of an input 1636 nm Hermite-Gaussian mode from the zeroth order to the first order using two periodically poled LiNbO(3) crystals. Nonlinear mode convers...
متن کاملCatalytic conversion of 1,2-dichlorobenzene over mesoporous materials from zeolite.
In this study, 1,2-dichlorobenzene (DCB), an important precursor of PCDDs and PCDFs, was chosen as a suitable model compound for the catalyzed deep oxidation of dioxin. The recently developed mesoporous materials from zeolites (MMZ) were used for the first time as a support for an oxidation catalyst. The catalytic oxidation of 1,2-dichlorobenzene over Pt/MMZ was carried out, and the catalytic a...
متن کاملMesoporous zeolite and zeotype single crystals synthesized in fluoride media
We report the synthesis and characterization of a series of new mesoporous zeolite and zeotype materials made available by combining new and improved procedures for directly introducing carbon into reaction mixtures with the fluoride route for conventional zeolite synthesis. The mesoporous materials were all prepared by hydrothermal crystallization of gels adsorbed on carbon matrices which were...
متن کاملStrongly Nonlinear Waves in 3d Phononic Crystals
Three dimensional phononic crystal ("sonic vacuum" without prestress) was assembled from 137 vertical cavities arranged in hexagonal pattern in Silicone matrix filled with stainless steel spheres. This system has unique strongly nonlinear properties with respect to wave propagation inherited from nonlinear Hertz type elastic contact interaction. Trains of strongly nonlinear solitary waves excit...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2011
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja2088025